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关键词:
Heterocyclic Chemistry, 5Th Edition
书目信息
ISBN:
9781405133005
本馆索书号:
中图分类号:
O6
中文译名:
作者:
John A. Joule
编者:
语种:
英语
出版信息
出版社:
Wiley-Blackwell
出版地:
出版年:
2010
版本:
版本类型:
原版
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卷期:
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前言:
摘要:
The preparation of a Fifth Edition of Heterocyclic Chemistry has allowed the authors to review thoroughly the material included in the earlier Editions, to make amendments in the light of new knowledge, and to include much recent work. Within the restriction that space dictates, all of the most significant heterocyclic chemistry of the 20th Century and many important 21st Century advances are covered. The principal aim of the earlier Editions to teach the fundamentals of heterocyclic reactivity and synthesis in a way that is understandable by undergraduate students has been maintained. However, much heterocyclic chemistry is now normally taught at advanced undergraduate, or post-graduate level, so more advanced and current material is included which make the book a reference text for such students and also for professional chemists involved in heterocyclic chemistry in the work place. Essential teaching material in the early chapters aims to capture the essence of heterocyclic reactivity in concise resumes suitable either as introductions, or as revisions/summaries for examination preparation. These early chapters are followed by detailed, systematic discussions of the chemical reactivity of particular heterocyclic systems. New in this Edition is the use of colour in the schemes. Those parts of products (or intermediates) where a change in structure or bonding has taken place are highlighted in red. This both facilitates comprehension and understanding of the chemical changes that are occurring and, especially for the undergraduate student, quickly focuses attention on just those parts of the molecules where structural change has occurred. Innovations in this 5th Edition include entirely new chapters dealing with (1) Organometallic heterocyclic chemistry, divided into two sections: (i) transition metal-catalysed processes and (ii) the generation and uses of heterocyclic organometallic nucleophiles, (2) Heterocycles in medicine, reflecting the large part that heterocyclic chemistry plays in the pharmaceutical industry, and (3) Heterocycles in biochemistry; heterocyclic natural products. Also included are new sections dealing explicitly with a number of topics important in the heterocyclic context: (i) heterocyclic fluorine compounds, (ii) isotopically labeled heterocycles, and (iii) the modern techniques of solid-phase chemistry, microwave heating and flow reactors. As in previous editions, the main body of factual material is to be found in chapters entitled 'Reactions and synthesis of pyridines, Reactions and synthesis of pyrroles, etc. Didactic material aimed especially at undergraduates, is contained in six short summary chapters, such as 'Typical reactivity of pyridines, quinolines, and isoquinolines', Typical reactivity of pyrroles, thiophenes, and furans, etc., which capture the essence of that typical reactivity in concise resumés. Early in the book there are also instructional chapters dealing with Structures and spectroscopic properties of aromatic heterocycles, Substitutions of aromatic heterocycles, Ring synthesis of aromatic heterocycles , together with the very important, Organometallic heterocyclic chemistry chapter. More than 4000 references are given: some of the references to original work are useful leading references, others are included as benchmark papers, and a few for their historical interest. Many references to reviews are also included. Exercises are given at the ends of the Reactions and synthesis of . chapters, some straightforward, revision exercises and some more advanced problems, with solutions given in an Appendix. This book has so closely matched the requirements of its readership over the years that it has become the first choice for chemists all over the world.
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http://www.itextbook.cn/f/book/bookDetail?bookId=e2d19779faf44ea68a86f06604fa4903
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